锂离子二次电池及其正极材料结构与性能研究

研究了锂离子二次电池的结构与性能、电化学反应原理 ,并对影响锂离子二次电池性能的几个问题作了探讨。同时 ,论述了其正极材料的研究及其主要制备方法。     

Effect of multiple reflows on interfacial reaction and shear strength of Sn-Ag electroplated solder bumps for flip chip package

The effect of displacement rate and intermetallic compound (IMC) growth on the shear strength of electroplated Sn-2.5Ag (in wt.%) flip chip solder with Cu under-bump metallization (UBM) were investigated after multiple reflows. Cu₆Sn₅ IMC was formed at the interface after one reflow. After five reflows, two different IMC layers, consisting of a scallop-shaped Cu₆Sn₅ phase and a planar Cu₃Sn phase, and their thicknesses increased with increasing reflow number up to 10. The shear strengths peaked after four reflows, and then decreased with increasing reflow number. Increasing displacement rate increased the shear force. The tendency toward brittle fracture characteristics was intensified with increasing displacement rate and reflow number.     

剥离型聚丙烯-蒙脱土纳米复合材料Ⅰ.Ziegler-Natta/有机改性蒙脱土复合催化剂催化丙烯聚合

采用化学反应法制备了Z ieg ler-Natta/有机咪唑盐改性蒙脱土复合催化剂(简称复合催化剂),并通过丙烯单体原位插层聚合制备了聚丙烯-蒙脱土纳米复合材料。考察了n(A l)∶n(T i)、聚合温度、聚合时间及溶剂种类对复合催化剂的活性及定向催化能力的影响。研究结果表明,与商品化CS-2型Zieg ler-Natta催化剂相比,复合催化剂的活性明显降低,在n(A l)∶n(T i)=100、聚合温度60℃、聚合时间1h、正庚烷为溶剂时,复合催化剂的活性较高,可达78.4kg/(m ol.h)。合成聚丙烯的等规度在85%~97%之间,熔融温度在160℃左右,重均相对分子质量达到(3.6~4.6)×105,相对分子质量分布在6.1~6.6之间。溶剂种类对合成聚丙烯的等规度影响较大。     

氮化物对柴油深度和超深度加氢脱硫的影响 Ⅱ 工艺条件和催化剂的影响

 采用硅胶脱除原料中氮化物，得到硫含量相同而氮含量不同的4种柴油原料。为了考察不同的催化剂、反应温度和氢分压条件下，氮化物对加氢脱硫(HDS)反应的影响，在330~370℃、2.0~6.4MPa、液时空速2.0h-1、氢/油体积比300的条件下，分别采用NiW/Al2O3和CoMo/Al2O3催化剂在小型固定床实验装置上，对4种柴油原料进行HDS反应。结果表明，氮化物对HDS反应有明显的抑制作用，但在两种催化剂上氮化物对HDS反应的抑制作用大小在不同的反应条件下的变化是不同的。当反应温度高于340℃或氢分压高于4.8MPa时，氮化物对CoMo/Al2O3 HDS活性的抑制作用大于对NiW/Al2O3上HDS活性的抑制作用；当氢分压低于3.2MPa时，氮化物对NiW/Al2O3 HDS活性的抑制作用较大。     

双模主动复合寻的制导技术研究

随着光电干扰、光电侦察技术的发展,现代战争中导弹作战环境变得十分复杂和恶劣。单一寻的模式的导引头难以完成对目标的全面探测和跟踪,必须采用双模或多模复合导引头。文中主要围绕双波段主动雷达导引头展开研究,旨在为远程反舰导弹提供一可行的高性能导引头方案,并进行必要的论证和相应技术研究。     

纳米铜/聚醋酸乙烯酯复合材料的制备与表征

以聚醋酸乙烯酯(PVAc)为配体,与CuC l2在乙醇溶液中进行反应,生成PVAc-Cu(Ⅱ)配合物。合成反应在室温下进行,反应时间以2 h为宜;用电导率法得出PVAc-Cu(Ⅱ)配合物中金属离子与PVAc链节单元CH2CH(OCOCH3)的物质的量之比为1∶4。以次亚磷酸钠为还原剂,在回流条件下对新合成的PVAc-Cu(Ⅱ)配合物进行还原,制得纳米铜/聚醋酸乙烯酯复合材料。IR分析表明:PVAc-Cu(Ⅱ)配合物中PVAc链节中的CH3COO—中的羰基氧提供孤对电子与金属离子Cu(Ⅱ)形成配位键。用透射电子显微镜(TEM)对纳米铜/聚醋酸乙烯酯复合材料进行表征,结果表明,复合材料中铜粒子的粒径在12.5~37.5 nm范围。     

SOS–A sample ordering system for delivering “assay-ready” compound plates for drug screening

Many bottlenecks in drug discovery have been addressed with the advent of new assay and instrument technologies. However, storing and processing chemical compounds for screening remains a challenge for many drug discovery laboratories. Although automated storage and retrieval systems are commercially available for medium to large collections of chemical samples, these samples are usually stored at a central site and are not readily accessible to satellite research labs.Drug discovery relies on the rapid testing of new chemical compounds in relevant biological assays. Therefore, newly synthesized compounds must be readily available in various formats to biologists performing screening assays. Until recently, our compounds were distributed in screw cap vials to assayists who would then manually transfer and dilute each sample in an “assay-ready” compound plate for screening. The vials would then be managed by the individuals in an ad hoc manner.To relieve the assayist from searching for compounds and preparing their own assay-ready compound plates, a newly customized compound storage system with an ordering software application was implemented at our research facility that eliminates these bottlenecks. The system stores and retrieves compounds in 1 mL-mini-tubes or microtiter plates, facilitates compound searching by identifier or structure, orders compounds at varying concentrations in specified wells on 96- or 384-well plates, requests the addition of controls (vehicle or reference compounds), etc. The orders are automatically processed and delivered to the assayist the following day for screening. An overview of our system will demonstrate that we minimize compound waste and ensure compound integrity and availability.     

定量荧光录井技术的回顾与展望

利用常规荧光检测仪进行荧光录井是识别油气层最方便易行的方法。以荧光检测仪为主线，系统回顾了定量荧光录井技术的发展历程，重点介绍了不同发展阶段定量荧光检测仪的结构原理、功能特点和应用情况，指出三维荧光检测仪将成为定量荧光录井的主流仪器，加强定量荧光录井资料的综合应用、开发定量荧光录井配套软件是定量荧光录井技术的发展趋势和今后努力的方向。     

16型异相游梁复合平衡抽油机性能测试

根据我国油田的开发现状及抽油机的应用情况 ,提出了 16型抽油机改进设计方法 ,并对改进后的CYJY16— 5 4— 89HF B型异相游梁复合平衡抽油机进行了整机性能测试 ,测试结果表明 ,该型抽油机的各项性能指标均符合SY T5 0 4 4— 93《游梁式抽油机》及SY T5 2 12— 97《游梁式抽油机质量分等》标准之要求。现场应用表明 ,该 16型抽油机与常规抽油机相比 ,减速器峰值扭矩下降 4 2 %以上 ,节能 30 %以上 ,并且结构简单、承载能力大、可靠性高。     

线性体聚合氨基硅油的合成与应用研究

利用线性体氨基硅油聚合原理合成了原油，然后将其与乳化剂以质量比2：1混合，高速搅拌制成20％含固量的线性体氨基硅油微乳液，将该微乳液与采用DMC、进口D4等按同样方法制成的氨基硅油微乳液进行了性能对比试验，结果表明：利用线性体制作的氨基硅油同时兼有羟基硅油和氨基硅油的性能，其硅油微乳液具有极好的滑爽性和柔软性。